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IBM Scientists Build World's First Single-Molecule Computer Circuit

Yorktown Heights, N.Y., August 26 , 2001
... IBM researchers today announced they have created and demonstrated the world's first logic-performing computer circuit within a single molecule, which may someday lead to a new class of smaller and faster computers that consume less power than today's machines. The IBM team made a " voltage inverter " -- one of the three fundamental logic circuits that are the basis for all of today's computers -- from a carbon nanotube, a tube-shaped molecule of carbon atoms that is 100,000 times thinner than a human hair. IBM scientists will present the achievement today at the 222nd National Meeting of the American Chemical Society being held in Chicago and it appears in the web edition of the ACS' journal Nano Letters.

This is the second major research breakthrough this year by IBM scientists using carbon nanotubes to make tiny electronic devices. In April, the same IBM team became the first to develop a ground breaking technique (Science, Vol. 292, Issue 5517, April 27, 2001) to produce arrays of carbon nanotube transistors, bypassing the need to meticulously separate metallic and semiconducting nanotubes. The team used these nanotube transistors to make the circuit revealed today.

"Carbon nanotubes are now the top candidate to replace silicon when current chip features just can't be made any smaller, a physical barrier expected to occur in about 10 to 15 years," said Dr. Phaedon Avouris, lead scientist on the project and manager of nanoscale science, IBM Research. "Such 'beyond silicon' nanotube electronics may then lead to unimagined progress in computing miniaturization and power."

Building a Computer Circuit "Inverter" Out of Carbon Nanotubes
The IBM scientists used nanotubes to make a "voltage inverter" circuit, also known as a "NOT" gate . They encoded the entire inverter logic function along the length of a single carbon nanotube, forming the world's first intra-molecular -- or single-molecule -- logic circuit. In the binary digital world of zeros and ones, a voltage inverter changes a '1' into a '0', and a ' 0' into a '1' inside computer chips. The processors at the heart of today' s computers are basically vast and intricate combinations of the NOT gate, with two other basic functions, "AND" and "OR" gates, which perform other computations.

Voltage inverters typically comprise two types of transistors with different electronic properties – "n-type" (in which electrons carry the electrical current) and "p-type" (in which electron-deficient regions called "holes" carry the electrical current). All previous carbon nanotube transistors have been p-type only. These transistors, while fine for scientific studies, are not sufficient to build logic-performing computer circuits. Scientists at IBM and elsewhere have been able to alter the properties of nanotube transistors by adding atoms of another element, such as potassium, to the carbon nanotube. However, Avouris' team recently discovered a new, simpler way to convert p-type nanotube transistors into n-type transistors. They found that they could simply heat p-type transistors in a vacuum, which turns them into n-type transistors and that they could reverse this process by exposing the transistors to air.

The team also discovered that in addition to converting an entire nanotube from p-type to n-type, they could also selectively convert part of a single nanotube to n-type, leaving the remaining part of the single nanotube p-type. The researchers used this process to build the world's first single-molecule logic circuit.

More importantly, the output signal from IBM's new nanotube circuit is stronger than the input. This phenomenon, called "gain," is essential for assembling gates and other circuit elements into useful microprocessors. Circuits with a gain less than one are ultimately useless -- the electrical signal becomes so faint that it cannot be detected. Since IBM's nanotube circuit has a gain of 1.6, Avouris is hopeful that even more complex circuits could be made along single nanotubes.

The IBM team is now working to create these more complex circuits, which is the next step toward molecular computers. In addition, the team is working to further improve the performance of individual nanotube transistors, and further integrate them into more complex circuits.

The report on this work "Carbon nanotube inter- and intra-molecular logic gates" by Vincent Derycke, Richard Martel, Joerg Appenzeller and Phaedon Avouris of IBM's T.J. Watson Research Center in Yorktown Heights, N.Y. was published in the August 26 Web edition of Nano Letters, a peer reviewed journal of the American Chemical Society, the world's largest scientific society. The online version is available at http://pubs.acs.org/nano. The work was also presented in Chicago at the 222nd national meeting of the American Chemical Society , August 26 during a symposium on "Molecular Electronics."

  
  At a glance...
Atomic Force Microscope image showing the design of an intra-molecular logic gate. A single carbon nanotube (shaded in blue) is positioned over gold electrodes to produce two p-type carbon nanotube field-effect transistors in series. The device is covered by an insulated layer (called PMMA) and a window is opened by e-beam lithography to expose part of the nanotube. Potassium is then evaporated through this window to convert the exposed p-type nanotube transistor into an n-type nanotube transistor, while the other nanotube transistor remains p-type.

Characteristics of the resulting intra-molecular voltage inverter. Open red circles are raw data for five different measurements on the same device (V=±2V). The blue line is the average of these five measurements. The thin straight line corresponds to an output/input gain of one.

·  Chip Evolution: IBM Scientists Develop Breakthrough Transistor Technology with Carbon Nanotubes

·  Carbon Nanotube Publications

·  Nano Letters (American Chemical Society)

IBM's Intra-Molecular Logic-Performing Computer Circuit
(The world's first single-molecule computer circuit)

       
(a) Atomic Force Microscope image showing the design of an intra-molecular logic gate. A single carbon nanotube (shaded in blue) is positioned over gold electrodes to produce two p-type carbon nanotube field-effect transistors in series. The device is covered by an insulated layer (called PMMA) and a window is opened by e-beam lithography to expose part of the nanotube. Potassium is then evaporated through this window to convert the exposed p-type nanotube transistor into an n-type nanotube transistor, while the other nanotube transistor remains p-type. (b) Characteristics of the resulting intra-molecular voltage inverter. Open red circles are raw data for five different measurements on the same device (V=±2V). The blue line is the average of these five measurements. The thin straight line corresponds to an output/input gain of one.

IMAGES FOR TECHNICAL PRESS

IBM's Inter-Molecular Logic Circuit
     
Fabrication of a voltage inverter (“NOT” logic gate ) using two nanotube field-effect transistors. Initially the two nanotube transistors are p-type. One of the them is protected by an insulating layer, the other is not.
(a) Placing the nanotubes in a vacuum converts the p-type nanotube transistors to n-type.
(b) The two CNTFETs are then exposed to oxygen (10-3 Torr of oxygen for 3 minutes). The unprotected n-type nanotube transistor (black curve) converts back to the original p-type, while the protected nanotube transistor (red curve) remains n-type.
(c) The two complementary (p-type and n-type) carbon nanotube transistors are wired as shown in the schematic.
(d) characteristics of the resulting inter-molecular inverter (V=1.5 V).



       
Electrical characteristics of n-type nanotube FETs made by:
(a) annealing (heating) the device in vacuum at 700 Kelvin for 10 minutes.
(b) doping with potassium.
The curves are obtained at different values of VDS starting for (a) from 300 mV, step size 200 mV and for (b) at 200 mV, step size 200 mV.

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